Structural determination and electronic properties of 4d perovskite SrPdO3

The structure and ground state electronic structure of the recently synthesized SrPdO$_3$ perovskite [A. Galal {\em et al.}, J. Power Sources, {\bf 195}, 3806 (2010)] have been studied by means of screened hybrid functional and the GW approximation with the inclusion of electron-hole interaction within the test-charge/test-charge scheme. By conducting a structural search based on lattice dynamics and group theoretical method we identify the orthorhombic phase with $P_{nma}$ space group as the most stable crystal structure. The phase transition from the ideal cubic perovskite structure to the $P_{nma}$ one is explained in terms of the simultaneous stabilization of the antiferrodistortive phonon modes $R_4^+$ and $M_3^+$. Our results indicate that SrPdO$_3$ exhibits an insulating ground state, substantiated by a GW$_0$ gap of about 1.1 eV. Spin polarized calculations suggests that SrPdO$_3$ adopts a low spin state ($t_{2g}^{\uparrow\downarrow\uparrow\downarrow\uparrow\downarrow}e_g^0$), and is expected to exhibit spin excitations and spin state crossovers at finite temperature, analogous to the case of 3$d$ isoelectronic LaCoO$_3$. This would provide a new playground for the study of spin state transitions in 4$d$ oxides and new opportunity to design multifunctional materials based on 4$d$ $P_{nma}$ building block

Time changes of symmetric diffusions and Feller measures

We extend the classical Douglas integral, which expresses the Dirichlet integral of a harmonic function on the unit disk in terms of its value on boundary, to the case of conservative symmetric diffusion in terms of Feller measure, by using the approach of time change of Markov processes.Comment: Published at http://dx.doi.org/10.1214/009117904000000649 in the Annals of Probability (http://www.imstat.org/aop/) by the Institute of Mathematical Statistics (http://www.imstat.org

Scatterer induced mode splitting in poly(dimethylsiloxane) coated microresonators

We investigate scatterer induced mode splitting in a composite microtoroidal resonator (Q ~ 10^6) fabricated by coating a silica microtoroid (Q ~ 10^7) with a thin poly(dimethylsiloxane) layer. We show that the two split modes in both coated and uncoated silica microtoroids respond in the same way to the changes in the environmental temperature. This provides a self-referencing scheme which is robust to temperature perturbations. Together with the versatile functionalities of polymer materials, mode splitting in polymer and polymer coated microresonators offers an attractive sensing platform that is robust to thermal noise.Comment: 9 pages, 3 figures, 15 reference

Estimation of Purcell factor from mode-splitting spectra in an optical microcavity

We investigate scattering process in an ultra-high-Q optical microcavity coupled to subwavelength scatterers by introducing "splitting quality" Qsp, a dimensionless parameter defined as the ratio of the scatterer-induced mode splitting to the total loss of the coupled system. A simple relation is introduced to directly estimate the Purcell factor from single-shot measurement of transmission spectrum of scatterer-coupled cavity. Experiments with polystyrene (PS) and gold (Au) nanoparticles, Erbium ions and Influenza A virions show that Purcell-factor-enhanced preferential funneling of scattering into the cavity mode takes place regardless of the scatterer type. Experimentally determined highest Qsp for single PS and Au nanoparticles are 9.4 and 16.19 corresponding to Purcell factors with lower bounds of 353 and 1049, respectively. The highest observed Qsp was 31.2 for an ensemble of Au particles. These values are the highest Qsp and Purcell factors reported up to date.Comment: 5 Pages, 4 Figures, 12 Reference

Regional Finance and Regional Disparities in China

China’s growth has been spectacularly high and persistent over the last few decades. However, there have been regular expressions of concern about the uneven distribution of the benefits across regions and, at times, it has been asserted that the regional distribution of available investment funds has played an important role – national financial institutions (mainly state-owned banks) have redirected deposits from the inland to loans to large institutions in the more prosperous coastal regions. At the same time, smaller regionally-focussed institutions are likely to improve the distribution of funds. We use a panel data set disaggregated by province for the years 1986 to 2004 to test these propositions. We employ recent panel unit roots and cointegration tests using data for state-owned bank loans as well as loans by rural credit cooperatives. We find that financial disparities are related to output disparities, that this relationship is positive, that it is stronger for rural credit cooperatives than for state-owned banks and that this relationship is causal in both the long and short runs. A reduction in financial disparities can be expected to lead a narrowing of output disparities in the short run and in the long run with the effect being larger for rural credit cooperatives than for state-owned commercial banks.regional disparities, panel econometrics, regional finance, China

Exceptionally strong magnetism in 4d perovskites RTcO3 (R=Ca,Sr,Ba)

The evolution of the magnetic ordering temperature of the 4d3 perovskites RTcO3 (R=Ca,Sr,Ba) and its relation with its electronic and structural properties has been studied by means of hybrid density functional theory and Monte Carlo simulations. When compared to the most widely studied 3d perovskites the large spatial extent of the 4d shells and their relatively strong hybridization with oxygen weaken the tendency to form Jahn-Teller like orbital ordering. This strengthens the superexchange interaction. The resulting insulating G-type antiferromagnetic ground state is characterized by large superexchange coupling constants (26-35 meV) and Neel temperatures (750-1200 K). These monotonically increase as a function of the R ionic radius due to the progressive enhancement of the volume and the associated decrease of the cooperative rotation of the TcO6 octahedra.Comment: 4 pages, 3 figure